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Physical organic chemistry

Physical organic chemistry is the study of the interrelationships between structure and reactivity in organic molecules. It a part of organic chemistry by using tools of physical chemistry such as chemical equilibrium, chemical kinetics, thermochemistry, and quantum chemistry.

Contributors in Physical organic chemistry

Physical organic chemistry

Cycloelimination

Chemistry; Physical organic chemistry

The reverse of cycloaddition. The term is preferred to the synonyms "cycloreversion", "retro-addition", and "retrocycloaddition".

Diamagnetic

Chemistry; Physical organic chemistry

Substances having a negative magnetic susceptibility are diamagnetic. They are repelled out of a magnetic field.

Cyclization

Chemistry; Physical organic chemistry

Formation of a ring compound from a chain by formation of a new bond.

Dienophile

Chemistry; Physical organic chemistry

The olefin component of a Diels-Alder reaction.

Detachment

Chemistry; Physical organic chemistry

The reverse of an attachment.

Encounter-controlled rate

Chemistry; Physical organic chemistry

A rate of reaction corresponding to the rate of encounter of the reacting molecular entities. This is also known as "diffusion-controlled rate" since rates of encounter are themselves controlled by ...

Arrhenius energy of activation

Chemistry; Physical organic chemistry

E a (SI unit: kJ mol -1 ) An operationally defined quantity expressing the dependence of a rate constant on temperature according to E a = RT 2 (∂ ln k /∂T) p as derived from the "Arrhenius ...

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