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Autoprotolysis

Transfer of a hydrogen ion between molecules of the same substance, e.g. the autoprotolysis of methanol (2 CH3OH = CH3OH2+ + CH3O-). Autoprotolysis of water into hydronium ions and hydroxide ions results in equilibrium concentrations that satisfy Kw = (H3O+)(OH-), where the autoprotolysis constant Kw is equal to 1.01 × 10-14 at 25°C.

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