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Diethyl ketone
A volatile organic compounds whose formula is C5H10O. It is released from combustion exhaust and solvent use. This is a compound that undergoes photolysis around the wavelengths of 302-320 nm and produces the acyl radical. That reactive species reacts with molecular oxygen to form a peroxide which can oxidise NO to NO2 :
CH3CH2C(=O)CH2CH3 + hv ---> CH3CH2C(=O). + CH3CH2.
CH3CH2C(=O). + O2 ---> CH3CH2C(=O)O2.
CH3CH2C(=O)O2. + NO ---> NO2 + CH3CH2CO2.
And finally the acylate radical CH3CH2CO2. can further oxidise NO to NO2, providing even more ammunition to make ozone while the sun shines (see nitrogen dioxide and ozone). ~Subramanian, M. S. ; Environmental Chemistry Analysis; Module 3. 3 Organic Air Pollutants; Department of CHemistry; India Institute of Technology, Madras, India`
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- Industry/Domain: Chemistry; Weather
- Category: Atmospheric chemistry
- Educational Institution: Sam Houston State University
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